LEPMI - Rubrique EIP Physicochimie 2022

Fuel cells

Work is being carried out on various aspects of ‘low-temperature’ fuel cells using polymer membranes. In acidic environments, for proton exchange membrane fuel cells (PEMFC), research is focusing on increasing the operating temperature to around 95°C for better heat flow management in heavy-duty applications (buses, lorries, trains, aircraft, etc.). In alkaline environments, work is being carried out on improving the use of platinum at the anode for hydrogen oxidation (HOR: hydrogen oxidation reaction), in particular through its encapsulation in carbon layers. Studies are also being conducted on hydrogen-rich fuels (sodium borohydride, hydrazine, etc.), which are themselves stable in alkaline environments and are being considered as alternatives to the direct use of H2.
Activité de nanoparticules Pd Activité de nanoparticules encapsulées Effet de forme sur l'efficacité d'une pile à combustible
The team is involved in the PEPR-H2 PEMFC95 project. This work is carried out through numerous collaborations, both academic and industrial.
Some recente publications:
  • Sgarbi, R. et al. Improved Activity and Durability of Carbon-Capped Pd and PdNi CatalystsFrom Model Active Layers to Anion-Exchange Membrane Fuel Cell Electrodes. ACS Catal. 15, 9379−9392 (2025). https://doi.org/10.1021/acscatal.5c00704
  • Oshchepkov, A. G., Braesch, G., Bonnefont, A., Savinova, E. R. & Chatenet, M. Recent Advances in the Understanding of Nickel-Based Catalysts for the Oxidation of Hydrogen-Containing Fuels in Alkaline Media. ACS Catal. 10, 7043-7068 (2020). https://doi.org:10.1021/acscatal.0c00101
  • Roiron, C., Martin, V., Kumar, K., Dubau, L. & Maillard, F. Assessing Pt and Ni dissolution mechanism and kinetics of shape-controlled oxygen reduction nanocatalysts. Electrochim. Acta 477 (2024). https://doi.org/10.1016/j.electacta.2024.143760
  • Labarde, Q., Godoy, A. O., Dubau, L., Micoud, F. & Chatenet, M. Carbon-Capped PtNi Catalysts for the Oxygen Reduction Reaction in Acidic Environment: A Durability Study. Electrocatal. 16, 117-131 (2025). https://doi.org/10.1007/s12678-024-00904-8