Magnesium Anthracene Systems Based-Electrolyte as promoter of High Electrochemical Performance Rechargeable Magnesium Batteries

The development of efficient, inexpensive, and safe rechargeable batteries for large-scale environmentally benign cells is one of the key requirements to accommodate and satisfy various technological applications. To date, the development of magnesium battery as a promising candidate for next-generation battery systems has been hindered by the lack of high performance and stable electrolyte. In this work, we have developed an original, safe, and high-performance class of electrolytes based on a simple mixture of commercially available compounds, that is, Mg(TFSI)₂, anthracene, MgCl₂, and diglyme solvent. We have proven that anthracene induces stabilization of the reduced form of magnesium involving reversible magnesium plating/stripping with very high current density. The electrolyte investigated exhibits an unprecedented electrochemical stability window of up to 3.1 V, whereas MgCl₂ addition allows the improvement of the Mg/electrolyte interface properties and enables a large cyclability of Mg/Mo₆S₈ Chevrel phase cell, allowing one to reach high performances.
doi.org/10.1021/acsami.7b16491